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Dimethylglyoxime is a chemical compound described by the formula CH3C(NOH)C(NOH)CH3. Its abbreviation is dmgH2 for neutral form, and dmgH for anionic form, where H stands for hydrogen. This colourless solid is the dioxime derivative of the diketone butane-2,3-dione (also known as diacetyl). DmgH2 is used in the analysis of palladium or nickel. https://ansxnw.weebly.com/how-to-download-apple-music-on-mac.html. Its coordination complexes are of theoretical interest as models for enzymes and as catalysts. Many related ligands can be prepared from other diketones, e.g. benzil.
Preparation[edit]
Dmg making a character generator. Dimethylglyoxime can be prepared from butanone first by reaction with ethyl nitrite to give biacetyl monoxime. https://potentselect571.weebly.com/best-archiver-program-for-mac.html. The second oxime is installed using sodium hydroxylamine monosulfonate:[1]
![]() Complexes[edit]
Dimethylglyoxime is used to detect and quantify nickel, which forms the bright red complex nickel bis(dimethylglyoximate) (Ni(dmgH)2). The reaction was discovered by L. A. Chugaev in 1905.[2] Populous the beginning pc game.
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Cobalt complexes have also received much attention. In chloro(pyridine)cobaloxime[3] the macrocycle [dmgH]22− Resnick halliday krane pdf. mimics the macrocyclic ligand found in vitamin B12.
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Structure of chloro(pyridine)cobaloxime.
References[edit]
Retrieved from 'https://en.wikipedia.org/w/index.php?title=Dimethylglyoxime&oldid=922963518'
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